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Coal-fired boilers are mainly operated at either subcritical or supercritical conditions. From a thermo-physics perspective, two phase mixtures of water and steam are replaced by a single supercritical fluid when the boiler pressure increases above the critical pressure of 22.12 MPa and the corresponding saturation temperature of 374 °C (Shen and Cheng, 2004).
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A gas-fired boiler provides hot water to taps throughout the home and also to radiators in the central heating system. Gas is an extremely efficient fuel and modern condensing boilers have large heat exchangers that collect and use almost all the heat created when the gas burns for heating and hot water, making the boilers 90% or more efficient.
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